๐งช Ester Nomenclature (IUPAC Rules)
① What is an Ester?
An ester is an organic compound derived from a carboxylic acid and an alcohol.
It has the general formula:
R–COO–R'
where R comes from the acid and R′ comes from the alcohol.
② Formation:
Esterification reaction:
Carboxylic acid + Alcohol → Ester + Water
Example:
CH₃COOH + CH₃OH → CH₃COOCH₃ + H₂O
③ IUPAC Naming Rules:
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Identify the alkyl group (R′) from the alcohol part → becomes the first word of the name.
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Identify the acid part (R–COO) and change the suffix “-ic acid” → “-ate.”
④ Examples:
Structure | Acid part | Alcohol part | IUPAC Name | Common Name |
---|---|---|---|---|
CH₃COOCH₃ | Ethanoic acid | Methanol | Methyl ethanoate | Methyl acetate |
CH₃COOC₂H₅ | Ethanoic acid | Ethanol | Ethyl ethanoate | Ethyl acetate |
C₂H₅COOCH₃ | Propanoic acid | Methanol | Methyl propanoate | — |
HCOOC₂H₅ | Methanoic acid | Ethanol | Ethyl methanoate | Ethyl formate |
⑤ General Formula of Ester:
CโH₂โO₂
⑥ Uses:
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Fragrances and perfumes (pleasant smell)
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Flavoring agents in food
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Solvents (e.g., ethyl acetate in nail polish remover)
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Plasticizers and pharmaceuticals
๐ณ️ Poll for Engagement:
Which feature of esters do you find most fascinating?
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๐ Their pleasant smell
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๐ Their role in chemistry
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๐ Their use as solvents
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๐ Their natural occurrence in fruits
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